The Charlotte Alumni Chapter has grown and evolved into one of the premier chapters within Kappa Alpha Psi under the leadership and vision of the following past chapter Polemarchs.
| Polemarch | Year(s) Served |
| Andrew J. Rollins * | 1944-1948 |
| Jack J. Benson * | 1948-1952 |
| Reginald A. Hawkins * | 1952-1958 |
| Howard C. Barnhill * | 1958-1965 |
| William M. Blakeney * | 1965-1970 |
| Ray A. Booton * | 1970-1971 |
| David Bratton * | 1971-1973 |
| Titus B. Ledbetter | 1973-1975 |
| Frank E. Gadsden | 1975-1977 |
| Rufus G. Pettis | 1977-1979 |
| James I. Melvin | 1979-1979 |
| Carl M. Flamer | 1979-1980 |
| Calvin Banks | 1980-1983 |
| Leroy Waters | 1983-1988 |
| R. Bernard Reeves | 1988-1992 |
| Sheldon L. “Jackpot” McAlpin | 1992-1993 |
| Edward “Eddie” Merritt | 1993-1996 |
| Dudley “Doug” Cunningham * | 1996-1998 |
| Frank J. Lawson | 1998-2000 |
| Willie G. “Will” Jones | 2000-2002 |
| C. N. “Pap” Parrish | 2002-2006 |
| Eugene “Gene” Price | 2006-2009 |
| Carlos D. Watson, Esq. | 2009-2011 |
| Richard Sumpter | 2011-2013 |
| William “Butch” Simmons | 2013-2015 |
| Anton L. Durrah | 2015-2018 |
| Olanda Carr, Jr. | 2018- |
* = Chapter invisible
